Investigation on the Stability of Supported Gold Nanoparticles

نویسندگان

  • Michela Signoretto
  • Federica Menegazzo
  • Valentina Trevisan
  • Francesco Pinna
  • Maela Manzoli
چکیده

The procedures leading to the preservation of catalytic performances of Au/ZrO2 samples have been investigated. The three potential causes of deactivation, namely the particle growth by sintering of gold nanoparticles, the metal leaching and the formation of un-reactive species which inhibit the reaction, have been evaluated. In particular, this paper deals with the stability of gold nanoparticles: (1) under storage conditions; (2) with time on stream for a gas phase reaction (LT-WGSR); (3) with time on stream for a liquid phase reaction (furfural oxidative esterification).

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تاریخ انتشار 2013